{"id":10616,"date":"2025-11-17T14:36:10","date_gmt":"2025-11-17T13:36:10","guid":{"rendered":"https:\/\/endolab.org\/?post_type=mt-polymer-analysis&#038;p=10616"},"modified":"2025-12-15T09:07:42","modified_gmt":"2025-12-15T08:07:42","slug":"astm-f2102","status":"publish","type":"mt-polymer-analysis","link":"https:\/\/endolab.org\/de\/mt-polymer-analysis\/astm-f2102\/","title":{"rendered":"ASTM F2102 \/ ISO 5834-4"},"content":{"rendered":"<p><strong>ASTM F2102:<\/strong> Standard Guide for evaluating the Extent of Oxidation in Polyethylene Fabricated Forms Intended for Surgical Implants<\/p>\n\n\n\n<p><strong>ISO 5834-4:<\/strong> Implants for surgery &#8211; Ultra-high-molecular-weight polyethylene &#8211; Part 4: Oxidation index measurement method<\/p>\n\n\n\n<div style=\"height:20px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<h4 class=\"wp-block-heading\">Purpose<\/h4>\n\n\n\n<p>ASTM F2102 provides a standardized approach for assessing the relative extent of oxidation in high-density polyethylene and ultra-high-molecular-weight polyethylene used in surgical implants. Oxidation is quantified through infrared spectroscopy, focusing on carbonyl groups that form as the material oxidizes.<\/p>\n\n\n\n<p>ISO 5834-4 is mostly interchangable with ASTM F2102. The only relevant difference is that it specifies a tolerance on the thickness of the specimen slice.<\/p>\n\n\n\n<div style=\"height:20px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<h4 class=\"wp-block-heading\">Typical Application<\/h4>\n\n\n\n<p>The guide is used for orthopedic implant components such as tibial inserts or hip bearings. It supports comparisons between different samples assuming that the samples have undergone oxidation via the same mechanisms (e.g. shelf aging, accelerated aging).<\/p>\n\n\n\n<div style=\"height:20px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<h4 class=\"wp-block-heading\">General Test Description<\/h4>\n\n\n\n<p>The method relies on Fourier Transform Infrared spectroscopy to measure the area of carbonyl absorptions near 1720 cm\u207b\u00b9, normalized to the C\u2013H absorption peak near 1370 cm\u207b\u00b9. Thin microtomed slices of about 200 \u00b5m are analyzed perpendicular to the surface of interest.<\/p>\n\n\n\n<p>A series of spectra is collected in depth increments that match the spectrometer\u2019s aperture, producing an oxidation index profile over the component\u2019s thickness. Key calculated values include surface oxidation index, bulk oxidation index, and maximum oxidation index. For retrieved components, lipid extraction is required to avoid overlap with lipid absorption peaks.<\/p>\n\n\n\n<div style=\"height:0px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<div style=\"height:20px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<h4 class=\"wp-block-heading\">Key Points<\/h4>\n\n\n\n<ul class=\"wp-block-list\">\n<li>Quantifies carbonyl-based oxidation via an area-based oxidation index.<\/li>\n\n\n\n<li>Provides definitions for oxidation index, depth locator, bulk and surface oxidation indices.<\/li>\n\n\n\n<li>Requires precise FTIR configuration, appropriate baseline handling, and validated scan numbers.<\/li>\n\n\n\n<li>Lipid extraction (heptane or hexane) is mandatory for retrieved or lipid-exposed samples.<\/li>\n<\/ul>\n\n\n\n<p><\/p>","protected":false},"featured_media":0,"parent":0,"template":"","meta":{"_acf_changed":false,"_uag_custom_page_level_css":""},"class_list":["post-10616","mt-polymer-analysis","type-mt-polymer-analysis","status-publish","hentry"],"acf":[],"uagb_featured_image_src":{"full":false,"thumbnail":false,"medium":false,"medium_large":false,"large":false,"1536x1536":false,"2048x2048":false,"trp-custom-language-flag":false},"uagb_author_info":{"display_name":"Kilian Pallauf","author_link":"https:\/\/endolab.org\/de\/author\/"},"uagb_comment_info":0,"uagb_excerpt":"ASTM F2102: Standard Guide for evaluating the Extent of Oxidation in Polyethylene Fabricated Forms Intended for Surgical Implants ISO 5834-4: Implants for surgery &#8211; Ultra-high-molecular-weight polyethylene &#8211; Part 4: Oxidation index measurement method Purpose ASTM F2102 provides a standardized approach for assessing the relative extent of oxidation in high-density polyethylene and ultra-high-molecular-weight polyethylene used in&hellip;","_links":{"self":[{"href":"https:\/\/endolab.org\/de\/wp-json\/wp\/v2\/mt-polymer-analysis\/10616","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/endolab.org\/de\/wp-json\/wp\/v2\/mt-polymer-analysis"}],"about":[{"href":"https:\/\/endolab.org\/de\/wp-json\/wp\/v2\/types\/mt-polymer-analysis"}],"wp:attachment":[{"href":"https:\/\/endolab.org\/de\/wp-json\/wp\/v2\/media?parent=10616"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}